I may have a similar issue with some .bin files from a statistical program Instat3 (GraphPad Software). Tech Tool Pro 4.5 reported all files to be fine but DW 4 said that three files were damaged and could not be repaired. May be the same issue because the program works fine.
On another note, there is another interesting glitch in file identification with DW 4. When you have a comparison of old and new directories in DW on PPC (2.3 GHz DP G5, 1 GB RAM, OS 10.4.8), the program correctly identifies Word 2004 files with a .doc suffix as Microsoft Word files. However, the Excel files with .xls suffix are identified as Unix executable files and their icons are shown as black rectangles. Did not have PowerPoint files at root level so cannot tell. Upon rebuilt, the Excel files show properly so it is probably not dramatic. Overall, Hal may be right that DW file checking is not perfect.
Alex
2 GHz MacBook Pro, 1 GB RAM, OS 10.4.8, Office 11.3.2
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Alex
2.66 GHz 17" MacBook Pro, 4 GB RAM, OS 10.5.7, Office 2008, TimeWarner Cable